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Registro Completo |
Biblioteca(s): |
Embrapa Florestas; Embrapa Solos. |
Data corrente: |
27/02/2013 |
Data da última atualização: |
26/09/2023 |
Tipo da produção científica: |
Artigo em Anais de Congresso |
Autoria: |
ALHO, C. F. B. V.; AUCCAISE, R.; MAIA, C. M. B. de F.; NOVOTNY, E. H.; LELIS, R. C. C. |
Afiliação: |
CARLOS FRANCISCO BRAZÃO VIEIRA ALHO, UNIVERSIDADE FEDERAL RURAL DO RIO DE JANEIRO; RUBEN AUCCAISE, BOLSISTA CNPS; CLAUDIA MARIA BRANCO DE F MAIA, CNPF; ETELVINO HENRIQUE NOVOTNY, CNPS; ROBERTO CARLOS COSTA LELIS, UNIVERSIDADE FEDERAL RURAL DO RIO DE JANEIRO. |
Título: |
Using solid state 13C NMR to study pyrolysis final temperature effects on biochar stability. |
Ano de publicação: |
2013 |
Fonte/Imprenta: |
In: XU, J.; WU, J.; HE, Y. (ed.). Functions of natural organic matter in changing environment. Dordrecht: Springer, 2013. p. 1007-1011. |
DOI: |
https://doi.org/10.1007/978-94-007-5634-2_186 |
Idioma: |
Inglês |
Conteúdo: |
Recent results in biochar research show that it is not only composed of stable carbon, since a portion of these materials is degraded relatively easily once applied to soil, and this condition is most dependent on pyrolysis conditions, especially the final temperature. Thus, the aim of this study was to evaluate pyrolysis final temperature effects on the stability of biochar produced from forest residues using solid-state 13C NMR. Pyrolysis was performed at a heating rate of 10°C·min-1 up to the final temperature of interest (350, 450 and 550°C), maintaining this temperature for 60 min. Solid-state 13C NMR spectra were obtained on a Varian 500-MHz spectrometer for fresh wood and biochars produced at 350, 450 and 550°C for Eucalyptus dunnii (DUN) and Pinus caribaea (CAR). Comparing fresh samples with their respective biochars, regardless of the botanical group, after pyrolysis, carbohydrates are degraded, and there is a change in the structure of the materials, with a predominance of aromatic structures, which are more resistant to degradation, therefore reflecting in the increased stability of these materials. For 350°C, it is still possible to observe signals related to lignin indicating that up to this temperature it has not been completely degraded. The spectra of biochars produced at 450 and 550°C are very similar, indicating that there is no need to produce biochars at very high final temperatures, since the structure of these materials obtained at 550°C slightly altered as of 450°C, keeping the predominance of aromatic structures. MenosRecent results in biochar research show that it is not only composed of stable carbon, since a portion of these materials is degraded relatively easily once applied to soil, and this condition is most dependent on pyrolysis conditions, especially the final temperature. Thus, the aim of this study was to evaluate pyrolysis final temperature effects on the stability of biochar produced from forest residues using solid-state 13C NMR. Pyrolysis was performed at a heating rate of 10°C·min-1 up to the final temperature of interest (350, 450 and 550°C), maintaining this temperature for 60 min. Solid-state 13C NMR spectra were obtained on a Varian 500-MHz spectrometer for fresh wood and biochars produced at 350, 450 and 550°C for Eucalyptus dunnii (DUN) and Pinus caribaea (CAR). Comparing fresh samples with their respective biochars, regardless of the botanical group, after pyrolysis, carbohydrates are degraded, and there is a change in the structure of the materials, with a predominance of aromatic structures, which are more resistant to degradation, therefore reflecting in the increased stability of these materials. For 350°C, it is still possible to observe signals related to lignin indicating that up to this temperature it has not been completely degraded. The spectra of biochars produced at 450 and 550°C are very similar, indicating that there is no need to produce biochars at very high final temperatures, since the structure of these materials obtained at 550°C slightly altere... Mostrar Tudo |
Palavras-Chave: |
Forest residues; NMR; Organic matter stability; Pyrogenic carbon. |
Thesaurus Nal: |
biochar. |
Categoria do assunto: |
P Recursos Naturais, Ciências Ambientais e da Terra |
Marc: |
LEADER 02379nam a2200229 a 4500 001 2156892 005 2023-09-26 008 2013 bl uuuu u00u1 u #d 024 7 $ahttps://doi.org/10.1007/978-94-007-5634-2_186$2DOI 100 1 $aALHO, C. F. B. V. 245 $aUsing solid state 13C NMR to study pyrolysis final temperature effects on biochar stability.$h[electronic resource] 260 $aIn: XU, J.; WU, J.; HE, Y. (ed.). Functions of natural organic matter in changing environment. Dordrecht: Springer, 2013. p. 1007-1011.$c2013 520 $aRecent results in biochar research show that it is not only composed of stable carbon, since a portion of these materials is degraded relatively easily once applied to soil, and this condition is most dependent on pyrolysis conditions, especially the final temperature. Thus, the aim of this study was to evaluate pyrolysis final temperature effects on the stability of biochar produced from forest residues using solid-state 13C NMR. Pyrolysis was performed at a heating rate of 10°C·min-1 up to the final temperature of interest (350, 450 and 550°C), maintaining this temperature for 60 min. Solid-state 13C NMR spectra were obtained on a Varian 500-MHz spectrometer for fresh wood and biochars produced at 350, 450 and 550°C for Eucalyptus dunnii (DUN) and Pinus caribaea (CAR). Comparing fresh samples with their respective biochars, regardless of the botanical group, after pyrolysis, carbohydrates are degraded, and there is a change in the structure of the materials, with a predominance of aromatic structures, which are more resistant to degradation, therefore reflecting in the increased stability of these materials. For 350°C, it is still possible to observe signals related to lignin indicating that up to this temperature it has not been completely degraded. The spectra of biochars produced at 450 and 550°C are very similar, indicating that there is no need to produce biochars at very high final temperatures, since the structure of these materials obtained at 550°C slightly altered as of 450°C, keeping the predominance of aromatic structures. 650 $abiochar 653 $aForest residues 653 $aNMR 653 $aOrganic matter stability 653 $aPyrogenic carbon 700 1 $aAUCCAISE, R. 700 1 $aMAIA, C. M. B. de F. 700 1 $aNOVOTNY, E. H. 700 1 $aLELIS, R. C. C.
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Registro original: |
Embrapa Florestas (CNPF) |
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Registros recuperados : 20 | |
9. | | ALHO, C. F. B. V.; FONTANA, A.; BENITES, V. de M.; PEREIRA, M. G.; LOSS, A.; BRITO, R. J. de. Caracterização de ácidos húmicos extraídos de solos sob diferentes coberturas vegetais no Norte fluminense. In: ENCONTRO BRASILEIRO DE SUBSTÂNCIAS HÚMICAS, 7., 2007, Florianópolis. As substâncias húmicas podem ajudar a salvar o planeta terra?: livro de resumos. Florianópolis: EBSH, 2007. p. 3.Tipo: Resumo em Anais de Congresso |
Biblioteca(s): Embrapa Solos. |
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12. | | ALHO, C. F. B. V.; CROOS, A.; SOHI, S.; ESTRADA, R. A.; NOVOTNY, E. H.; MAIA, C. M. B. de F.; LELIS, R. C. C. Biochar stable fraction quantification by thermo-chemical oxidation and assessement by 13C NMR spectrocopy. In: ENCONTRO BRASILEIRO DE SUBSTÂNCIAS HÚMICAS, 10., 2013, Santo Antônio de Goiás. Matéria orgânica e qualidade ambiental: anais. Brasília, DF: Embrapa, 2013. p. 340-343Tipo: Artigo em Anais de Congresso |
Biblioteca(s): Embrapa Florestas. |
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13. | | ALHO, C. F. B. V.; CROSS, A.; SOHI, S.; RODRIGUES, R. C.; NOVOTNY, E. H.; MAIA, C. M. B. de F.; LELIS, R. C. C. Biochar stable fraction quantification by thermochemical oxidation and assessement by 13C-NMR spectrocopy. In: ENCONTRO BRASILEIRO DE SUBSTÂNCIAS HÚMICAS, 10., Santo Antônio de Goiás, GO, 2013. Anais... Porto Alegre: Grupo Brasileiro da Sociedade Internacional de substâncias húmicas, 2013. 4p.Tipo: Resumo em Anais de Congresso |
Biblioteca(s): Embrapa Solos. |
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14. | | ALHO, C. F. B. V.; ARAÚJO, J. R.; ACHETE, C. A.; TEIXEIRA, W. G.; NOVOTNY, E. H.; PEREIRA, M. G.; HIEMSTRA, T.; KUYPER, T. W. Avaliação das características químicas da matéria orgânica do solo em Terra Preta de Índio por espectroscopia de fotoelétrons excitados por raios-X. In: ENCONTRO BRASILEIRO DE SUBSTÂNCIAS HÚMICAS, 11., 2015, São Carlos, SP. Substâncias húmicas, ciência e tecnologia: livro de resumos. São Carlos, SP: IQSC, 2015. p. 32-35.Tipo: Artigo em Anais de Congresso |
Biblioteca(s): Embrapa Solos. |
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15. | | ALHO, C. F. B. V.; CROSS, A.; SOHI, S. P.; MAIA, C. M. B. de F.; NOVOTNY, E. H.; LELIS, R. C. da C. Pyrolysis final temperature effects on biochar stability. In: ENCONTRO BRASILEIRO DE SUBSTÂNCIAS HÚMICAS, 9., 2011, Aracaju. Matéria orgânica natural e substâncias húmicas: dos avanços das técnicas de caracterização ao seqüestro de C. [Aracaju: UFS: IHSS, 2011]. 1 CD-ROM.Tipo: Artigo em Anais de Congresso |
Biblioteca(s): Embrapa Florestas; Embrapa Solos. |
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18. | | ALHO, C. F. B. V.; AUCCAISE, R.; MAIA, C. M. B. de F.; NOVOTNY, E. H.; LELIS, R. C. da C. Using solid state 13C to study pyrolysis final effects on bichar stability. In: MEETING OF THE INTERNATIONAL HUMIC SUBSTANCES SOCIETY, 16., 2012, Hangzhou, China. Functions of natural organic matter in changing environment. [S.l.]: Zhejiang University Press: Springer, 2012. p. 567-569. Editado por: Jianming Xu, Jianjun Wu, Yan He.Tipo: Artigo em Anais de Congresso |
Biblioteca(s): Embrapa Florestas. |
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19. | | ALHO, C. F. B. V.; FREITAS, A. C. R. de; SANTOS, F. C. dos; SILVEIRA, M. C. T. da; SANTI, A.; NASCIMENTO, A. F. do; ALVES, B. J. R.; MADARI, B. E. Performance of the Manure-DNDC model in estimating soil organic carbon stocks of (sub)tropical soils under different pedoclimatic zones and farming systems. In: CONGRESO INTERNACIONAL DE SISTEMAS SILVOPASTORILES, 12.; CONGRESO DE LA RED GLOBAL DE SISTEMAS SILVOPASTORILES, 2.; IV SEMINARIO NACIONAL DE SISTEMAS SILVOPASTORILES, 4., 2023, Montevideo; CONGRESO NACIONAL SISTEMAS SILVOPASTORILES, 5., 2023, Buenos Aires. Sistemas silvopastoriles: hacia una diversificación sostenible. Cali: CIPAV, 2023. p. 638.Tipo: Resumo em Anais de Congresso |
Biblioteca(s): Embrapa Agrobiologia; Embrapa Arroz e Feijão; Embrapa Milho e Sorgo; Embrapa Trigo. |
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20. | | LOMBARDO, U.; ARROYO-KALIN, M.; SCHMIDT, M.; HUISMAN, H.; LIMA, H. P.; MORAES, M. de P.; NEVES, E. G.; CLEMENT, C. R.; FONSECA, J. A. da; ALMEIDA, F. O. de; ALHO, C. F. B. V.; RAMSEY, C. B.; BROWN, G. G.; CAVALLINI, M. S.; COSTA, M. L. da; CUNHA, L.; ANJOS, L. H. C. dos; DENEVAN, W. M.; FAUSTO, C.; CAROMANO, C. F.; FONTANA, A.; FRANCHETTO, B.; GLASER, B.; HECKENBERGER, M. J.; HECHT, S.; HONORATO, V.; JAROSCH, K. A.; JUNQUEIRA, A. B.; KATER, T.; TAMANAHA, E. K.; KUYPER, T. W.; LEHMANN, J.; MADELLA, M.; MAEZUMI, S. Y.; CASCON, L. M.; MAYLE, F. E.; MCKEY, D.; MORAES, B.; MORCOTE-RÍOS, G.; BARBOSA, C. A. P.; MAGALHÃES, M. P.; PRESTES-CARNEIRO, G.; PUGLIESE, F.; PUPIM, F. N.; RACZKA, M. F.; PY-DANIEL, A. R.; ROCHA, B. C. da; RODRIGUES, L.; ROSTAIN, S.; MACEDO, R. S.; SHOCK, M. P.; SPRAFKE, T.; BASSI, F. S.; VALLE, R.; VIDAL-TORRADO, P.; VILLAGRÁN, X. S.; WATLING, J.; WEBER, S. L.; TEIXEIRA, W. G. Evidence confirms an anthropic origin of Amazonian Dark Earths. Nature Communications, v. 13, n. 3444, 2022. 6 p.Tipo: Nota Técnica/Nota Científica |
Biblioteca(s): Embrapa Florestas; Embrapa Solos. |
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Registros recuperados : 20 | |
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Nenhum registro encontrado para a expressão de busca informada. |
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